Information card for entry 4309433

Structure parameters

• Formula: C36 H34 Cl4 N8 O Rh2
• Calculated formula: C36 H34 Cl4 N8 O Rh2
• SMILES: [Rh]12(Cl)(Cl)(c3ccccc3N=[N]1c1ccccc1[NH2]2)[NH2]c1ccccc1.O
• Title of publication: Reactions of 2-(Arylazo) Aniline with RhCl3: Synthesis and Structure of New Cyclometalated Complexes of Rh(III) and Recognition of RhCl3 Assisted Azo (NN) Cleavage
• Authors of publication: Jahar lal Pratihar; Nilkamal Maiti; Surajit Chattopadhyay
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 6111 - 6114
• a: 12.251 ± 0.012 Å
• b: 12.438 ± 0.012 Å
• c: 13.836 ± 0.013 Å
• α: 91.21 ± 0.02°
• β: 98.51 ± 0.02°
• γ: 101.85 ± 0.03°
• Cell volume: 2038 ± 3 ų
• Cell temperature: 273 ± 2 K
• Ambient diffraction temperature: 273 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0698
• Residual factor for significantly intense reflections: 0.0396
• Weighted residual factors for significantly intense reflections: 0.0901
• Weighted residual factors for all reflections included in the refinement: 0.1025
• Goodness-of-fit parameter for all reflections included in the refinement: 1.021
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No