Information card for entry 4310563

Structure parameters

• Common name: [CeBr(Me3SiNSiMe3)3]
• Formula: C18 H54 Br Ce N3 Si6
• Calculated formula: C18 H54 Br Ce N3 Si6
• SMILES: Br[Ce](N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Oxidation in Nonclassical Organolanthanide Chemistry: Synthesis, Characterization, and X-ray Crystal Structures of Cerium(III) and -(IV) Amides
• Authors of publication: Peter B. Hitchcock; Alexander G. Hulkes; Michael F. Lappert
• Journal of publication: Inorganic Chemistry
• Year of publication: 2004
• Journal volume: 43
• Pages of publication: 1031 - 1038
• a: 18.4113 ± 0.0012 Å
• b: 18.4113 ± 0.0012 Å
• c: 16.9631 ± 0.0017 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 4979.7 ± 0.7 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 161
• Hermann-Mauguin space group symbol: R 3 c :H
• Hall space group symbol: R 3 -2"c
• Residual factor for all reflections: 0.0704
• Residual factor for significantly intense reflections: 0.0435
• Weighted residual factors for significantly intense reflections: 0.0807
• Weighted residual factors for all reflections included in the refinement: 0.0892
• Goodness-of-fit parameter for all reflections included in the refinement: 1.056
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No