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Information card for entry 4313807
Preview
Coordinates | 4313807.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C28 H26 B Cl F3 N7 O3 Os P S |
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Calculated formula | C28 H26 B Cl2 F3 N7 O3 Os P S |
SMILES | c1ccn2[BH]3n4ccc[n]4[Os]([n]12)([n]1cccn31)(N=P(c1ccccc1)(c1ccccc1)c1ccccc1)(Cl)Cl.C(F)(F)(F)S(=O)(=O)[O-] |
Title of publication | Osmium Phosphiniminato Complexes: Synthesis, Protonation, Structure, and Redox-Coupled Hydrolytic Scission of N-P Bonds |
Authors of publication | Brian K. Bennett; Erik Saganic; Scott Lovell; Werner Kaminsky; Amanda Samuel; James M. Mayer |
Journal of publication | Inorganic Chemistry |
Year of publication | 2003 |
Journal volume | 42 |
Pages of publication | 4127 - 4134 |
a | 18.0427 ± 0.0008 Å |
b | 9.8788 ± 0.0002 Å |
c | 19.5069 ± 0.0008 Å |
α | 90° |
β | 105.467 ± 0.001° |
γ | 90° |
Cell volume | 3351 ± 0.2 Å3 |
Cell temperature | 161 ± 2 K |
Ambient diffraction temperature | 161 ± 2 K |
Number of distinct elements | 10 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.1113 |
Residual factor for significantly intense reflections | 0.0561 |
Weighted residual factors for significantly intense reflections | 0.1029 |
Weighted residual factors for all reflections included in the refinement | 0.1215 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.076 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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