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Information card for entry 4313808
Preview
Coordinates | 4313808.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | BB-III-O4 |
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Formula | C27 H26 B Cl2 N7 Os P |
Calculated formula | C27 H26 B Cl2 N7 Os P |
SMILES | [BH]12n3ccc[n]3[Os]([n]3cccn13)([n]1cccn21)(N=P(c1ccccc1)(c1ccccc1)c1ccccc1)(Cl)Cl |
Title of publication | Osmium Phosphiniminato Complexes: Synthesis, Protonation, Structure, and Redox-Coupled Hydrolytic Scission of N-P Bonds |
Authors of publication | Brian K. Bennett; Erik Saganic; Scott Lovell; Werner Kaminsky; Amanda Samuel; James M. Mayer |
Journal of publication | Inorganic Chemistry |
Year of publication | 2003 |
Journal volume | 42 |
Pages of publication | 4127 - 4134 |
a | 8.756 ± 0.0004 Å |
b | 15.172 ± 0.0004 Å |
c | 20.913 ± 0.0011 Å |
α | 90° |
β | 96.9 ± 0.0017° |
γ | 90° |
Cell volume | 2758.1 ± 0.2 Å3 |
Cell temperature | 130 ± 2 K |
Ambient diffraction temperature | 130 ± 2 K |
Number of distinct elements | 7 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0833 |
Residual factor for significantly intense reflections | 0.042 |
Weighted residual factors for significantly intense reflections | 0.0653 |
Weighted residual factors for all reflections included in the refinement | 0.0729 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.88 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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