Information card for entry 4313809

Structure parameters

• Common name: AS8-06
• Formula: C14 H20 B Cl2 N7 O Os
• Calculated formula: C14 H20 B Cl2 N7 O Os
• SMILES: [BH]12n3ccc[n]3[Os]([n]3cccn13)([n]1cccn21)(N=C(C)OC(C)C)(Cl)Cl
• Title of publication: Osmium Phosphiniminato Complexes: Synthesis, Protonation, Structure, and Redox-Coupled Hydrolytic Scission of N-P Bonds
• Authors of publication: Brian K. Bennett; Erik Saganic; Scott Lovell; Werner Kaminsky; Amanda Samuel; James M. Mayer
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 4127 - 4134
• a: 8.672 ± 0.0005 Å
• b: 10.482 ± 0.0005 Å
• c: 11.199 ± 0.0004 Å
• α: 84.948 ± 0.003°
• β: 87.962 ± 0.003°
• γ: 77.062 ± 0.002°
• Cell volume: 988.16 ± 0.08 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0404
• Residual factor for significantly intense reflections: 0.034
• Weighted residual factors for significantly intense reflections: 0.0823
• Weighted residual factors for all reflections included in the refinement: 0.0845
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No