Information card for entry 4315123

Structure parameters

• Chemical name: tetrachlorosilane 1,10-phenanthroline complex, acetonitrile solvate
• Formula: C26 H19 Cl8 N5 Si2
• Calculated formula: C26 H19 Cl8 N5 Si2
• SMILES: Cl[Si]1(Cl)(Cl)(Cl)[n]2cccc3ccc4ccc[n]1c4c23.N#CC
• Title of publication: Reactions of Hydridochlorosilanes with 2,2'-Bipyridine and 1,10-Phenanthroline: Complexation versus Dismutation and Metal-Catalyst-Free 1,4-Hydrosilylation
• Authors of publication: Gerrit W. Fester; Jana Eckstein; Daniela Gerlach; Jörg Wagler; Erica Brendler; Edwin Kroke
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 2667 - 2673
• a: 7.4952 ± 0.001 Å
• b: 12.3284 ± 0.0018 Å
• c: 16.551 ± 0.002 Å
• α: 89.334 ± 0.005°
• β: 87.725 ± 0.004°
• γ: 78.77 ± 0.004°
• Cell volume: 1498.9 ± 0.3 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0621
• Residual factor for significantly intense reflections: 0.04
• Weighted residual factors for significantly intense reflections: 0.095
• Weighted residual factors for all reflections included in the refinement: 0.1018
• Goodness-of-fit parameter for all reflections included in the refinement: 1.105
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No