Information card for entry 4315124

Structure parameters

• Chemical name: trichlorosilane 2,2'-bipyridine complex
• Formula: C10 H9 Cl3 N2 Si
• Calculated formula: C10 H9 Cl3 N2 Si
• SMILES: Cl[SiH]1(Cl)(Cl)[n]2ccccc2c2[n]1cccc2
• Title of publication: Reactions of Hydridochlorosilanes with 2,2'-Bipyridine and 1,10-Phenanthroline: Complexation versus Dismutation and Metal-Catalyst-Free 1,4-Hydrosilylation
• Authors of publication: Gerrit W. Fester; Jana Eckstein; Daniela Gerlach; Jörg Wagler; Erica Brendler; Edwin Kroke
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 2667 - 2673
• a: 12.4724 ± 0.0006 Å
• b: 7.6648 ± 0.0003 Å
• c: 12.9933 ± 0.0006 Å
• α: 90°
• β: 95.94 ± 0.002°
• γ: 90°
• Cell volume: 1235.47 ± 0.1 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0606
• Residual factor for significantly intense reflections: 0.0451
• Weighted residual factors for significantly intense reflections: 0.11
• Weighted residual factors for all reflections included in the refinement: 0.1147
• Goodness-of-fit parameter for all reflections included in the refinement: 1.084
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No