Information card for entry 4316139

Structure parameters

• Common name: {(2,6-dimesitylphenyl)imidogermanium(II)}2
• Formula: C48 H50 Ge2 N2
• Calculated formula: C48 H50 Ge2 N2
• SMILES: [Ge]1N(c2c(cccc2c2c(cc(cc2C)C)C)c2c(cc(cc2C)C)C)[Ge]N1c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C
• Title of publication: Synthesis and Structural Characterization of a Series of Dimeric Metal(II) Imido Complexes {M(μ-NAr#)}2 [M = Ge, Sn, Pb; Ar#= C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido Derivatives M{N(H)Ar#}2 (M = Ge, Sn, Pb): Spectroscopic Manifestations of Secondary Metal-Ligand Interactions
• Authors of publication: William A. Merrill; Robert J. Wright; Corneliu S. Stanciu; Marilyn M. Olmstead; James C. Fettinger; Philip P. Power
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 7097 - 7105
• a: 11.1086 ± 0.0012 Å
• b: 11.9616 ± 0.0013 Å
• c: 15.657 ± 0.002 Å
• α: 93.649 ± 0.002°
• β: 91.118 ± 0.002°
• γ: 95.606 ± 0.002°
• Cell volume: 2065.6 ± 0.4 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0389
• Residual factor for significantly intense reflections: 0.0323
• Weighted residual factors for significantly intense reflections: 0.088
• Weighted residual factors for all reflections included in the refinement: 0.092
• Goodness-of-fit parameter for all reflections included in the refinement: 1.033
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No