Information card for entry 4316140

Structure parameters

• Common name: {(2,6-dimesitylphenyl)imidotin(II)}2
• Formula: C48 H50 N2 Sn2
• Calculated formula: C48 H50 N2 Sn2
• SMILES: [Sn]1N(c2c(cccc2c2c(cc(cc2C)C)C)c2c(cc(cc2C)C)C)[Sn]N1c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C
• Title of publication: Synthesis and Structural Characterization of a Series of Dimeric Metal(II) Imido Complexes {M(μ-NAr#)}2 [M = Ge, Sn, Pb; Ar#= C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido Derivatives M{N(H)Ar#}2 (M = Ge, Sn, Pb): Spectroscopic Manifestations of Secondary Metal-Ligand Interactions
• Authors of publication: William A. Merrill; Robert J. Wright; Corneliu S. Stanciu; Marilyn M. Olmstead; James C. Fettinger; Philip P. Power
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 7097 - 7105
• a: 12.6268 ± 0.0011 Å
• b: 21.102 ± 0.0019 Å
• c: 16.2797 ± 0.0014 Å
• α: 90°
• β: 111.47 ± 0.003°
• γ: 90°
• Cell volume: 4036.7 ± 0.6 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.083
• Residual factor for significantly intense reflections: 0.0449
• Weighted residual factors for significantly intense reflections: 0.0999
• Weighted residual factors for all reflections included in the refinement: 0.1177
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No