Information card for entry 4316986

Structure parameters

• Common name: amidinate silylene nickel carbony complex
• Chemical name: could not be determined
• Formula: C18 H23 Cl N2 Ni O3 Si
• Calculated formula: C18 H23 Cl N2 Ni O3 Si
• SMILES: [Ni](C#[O])(C#[O])(C#[O])[Si]1(Cl)N(C(=[N]1C(C)(C)C)c1ccccc1)C(C)(C)C
• Title of publication: Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes
• Authors of publication: Gašper Tavčar; Sakya S. Sen; Ramachandran Azhakar; Andrea Thorn; Herbert W. Roesky
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 10199 - 10202
• a: 13.942 ± 0.003 Å
• b: 11.524 ± 0.002 Å
• c: 13.737 ± 0.003 Å
• α: 90°
• β: 111.24 ± 0.03°
• γ: 90°
• Cell volume: 2057.2 ± 0.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0275
• Residual factor for significantly intense reflections: 0.0271
• Weighted residual factors for significantly intense reflections: 0.0753
• Weighted residual factors for all reflections included in the refinement: 0.0755
• Goodness-of-fit parameter for all reflections included in the refinement: 1.147
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No