Information card for entry 4316987

Structure parameters

• Common name: dipp carbene silylene nickel carbony complex
• Chemical name: could not be determined
• Formula: C63 H80 Cl4 N4 Ni O2 Si2
• Calculated formula: C63 H80 Cl4 N4 Ni O2 Si2
• Title of publication: Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes
• Authors of publication: Gašper Tavčar; Sakya S. Sen; Ramachandran Azhakar; Andrea Thorn; Herbert W. Roesky
• Journal of publication: Inorganic Chemistry
• Year of publication: 2010
• Journal volume: 49
• Pages of publication: 10199 - 10202
• a: 15.072 ± 0.003 Å
• b: 17.701 ± 0.004 Å
• c: 24.5 ± 0.005 Å
• α: 90°
• β: 95.46 ± 0.03°
• γ: 90°
• Cell volume: 6507 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0489
• Residual factor for significantly intense reflections: 0.0391
• Weighted residual factors for significantly intense reflections: 0.1066
• Weighted residual factors for all reflections included in the refinement: 0.1146
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No