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Information card for entry 4317404
Preview
Coordinates | 4317404.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C80 H52 N2 O28 P2 Rh10 |
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Calculated formula | C80 H52 N2 O28 P2 Rh10 |
SMILES | [NH2](CCCC[NH2][Rh]1234(C#[O])(C#[O])[Rh]5678(C#[O])([Rh]9%10%111(C#[O])([Rh]25(C#[O])([Rh]69(C#[O])(C#[O])(C#[O])C%11=O)(C4=O)(C8=O)C%10=O)C7=O)C3=O)[Rh]1234(C#[O])(C#[O])[Rh]5678(C#[O])(C1=O)C(=O)[Rh]19%1036(C#[O])[Rh]25(C#[O])([Rh]71(C#[O])(C#[O])(C#[O])C%10=O)(C4=O)(C9=O)C8=O.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Synthesis and Structural Characterization of the {[Rh5(CO)14]-(H2N(CH2)4NH2)-[Rh5(CO)14])}2- and [Rh5(CO)13(H2N(CH2)2NH2)]- Anions (as [PPh4]+ Salts): An Unprecedented Example of Carbonyl Substitution by Alkylamines in a Homoleptic Metal Carbonyl Cluster Anion |
Authors of publication | Alessandro Fumagalli; Maria Carlotta Malatesta; Anna Tentori; Diego Monti; Piero Macchi; Angelo Sironi |
Journal of publication | Inorganic Chemistry |
Year of publication | 2002 |
Journal volume | 41 |
Pages of publication | 76 - 85 |
a | 23.209 ± 0.003 Å |
b | 9.83 ± 0.001 Å |
c | 23.683 ± 0.003 Å |
α | 90° |
β | 110.23 ± 0.01° |
γ | 90° |
Cell volume | 5069.8 ± 1.1 Å3 |
Cell temperature | 298 ± 2 K |
Ambient diffraction temperature | 571 ± 2 K |
Number of distinct elements | 6 |
Space group number | 13 |
Hermann-Mauguin space group symbol | P 1 2/n 1 |
Hall space group symbol | -P 2yac |
Residual factor for all reflections | 0.0993 |
Residual factor for significantly intense reflections | 0.0492 |
Weighted residual factors for significantly intense reflections | 0.0833 |
Weighted residual factors for all reflections included in the refinement | 0.0944 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.972 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4317404.html
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