Information card for entry 4317405

Structure parameters

• Formula: C43 H36 N2 O14 P Rh5
• Calculated formula: C43 H36 N2 O14 P Rh5
• Title of publication: Synthesis and Structural Characterization of the {[Rh5(CO)14]-(H2N(CH2)4NH2)-[Rh5(CO)14])}2- and [Rh5(CO)13(H2N(CH2)2NH2)]- Anions (as [PPh4]+ Salts): An Unprecedented Example of Carbonyl Substitution by Alkylamines in a Homoleptic Metal Carbonyl Cluster Anion
• Authors of publication: Alessandro Fumagalli; Maria Carlotta Malatesta; Anna Tentori; Diego Monti; Piero Macchi; Angelo Sironi
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 76 - 85
• a: 11.999 ± 0.002 Å
• b: 12.76 ± 0.002 Å
• c: 16.919 ± 0.002 Å
• α: 99.94 ± 0.01°
• β: 101.4 ± 0.01°
• γ: 106.3 ± 0.01°
• Cell volume: 2364.5 ± 0.6 ų
• Cell temperature: 233 ± 2 K
• Ambient diffraction temperature: 233 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0388
• Residual factor for significantly intense reflections: 0.0229
• Weighted residual factors for significantly intense reflections: 0.0434
• Weighted residual factors for all reflections included in the refinement: 0.045
• Goodness-of-fit parameter for all reflections included in the refinement: 0.842
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No