Information card for entry 4318373

Structure parameters

• Chemical name: [Pt(PP3)CN]CN.H2O
• Formula: C44 H42 N2 O P4 Pt
• Calculated formula: C44 H42 N2 O P4 Pt
• Title of publication: Preparation and Structural Characterization of Ionic Five-Coordinate Palladium(II) and Platinum(II) Complexes of the Ligand Tris[2-(diphenylphosphino)ethyl]phosphine. Insertion of SnCl2 into M-Cl Bonds (M = Pd, Pt) and Hydroformylation Activity of the Pt-SnCl3 Systems
• Authors of publication: Damián Fernández; M. Inés García-Seijo; Tamás Kégl; György Petöcz; László Kollár; M. Esther García-Fernández
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 4435 - 4443
• a: 10.306 ± 0.004 Å
• b: 10.488 ± 0.004 Å
• c: 21.012 ± 0.008 Å
• α: 80.411 ± 0.006°
• β: 86.458 ± 0.006°
• γ: 76.204 ± 0.006°
• Cell volume: 2174.3 ± 1.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1336
• Residual factor for significantly intense reflections: 0.1126
• Weighted residual factors for significantly intense reflections: 0.292
• Weighted residual factors for all reflections included in the refinement: 0.3032
• Goodness-of-fit parameter for all reflections included in the refinement: 1.251
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No