Information card for entry 4318374

Structure parameters

• Chemical name: [Pt(PP3)(SnCl3)](SnCl3).CHCl3
• Formula: C43 H42 Cl9 P4 Pt Sn2
• Calculated formula: C43 H42 Cl9 P4 Pt Sn2
• SMILES: Cl[Sn]([Pt]123[P](c4ccccc4)(c4ccccc4)CC[P]1(CC[P]3(c1ccccc1)c1ccccc1)CC[P]2(c1ccccc1)c1ccccc1)(Cl)Cl.ClC(Cl)Cl.[Sn](Cl)(Cl)[Cl-]
• Title of publication: Preparation and Structural Characterization of Ionic Five-Coordinate Palladium(II) and Platinum(II) Complexes of the Ligand Tris[2-(diphenylphosphino)ethyl]phosphine. Insertion of SnCl2 into M-Cl Bonds (M = Pd, Pt) and Hydroformylation Activity of the Pt-SnCl3 Systems
• Authors of publication: Damián Fernández; M. Inés García-Seijo; Tamás Kégl; György Petöcz; László Kollár; M. Esther García-Fernández
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 4435 - 4443
• a: 12.514 ± 0.003 Å
• b: 42.38 ± 0.011 Å
• c: 10.552 ± 0.003 Å
• α: 90°
• β: 113.165 ± 0.004°
• γ: 90°
• Cell volume: 5145 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1267
• Residual factor for significantly intense reflections: 0.0658
• Weighted residual factors for significantly intense reflections: 0.1363
• Weighted residual factors for all reflections included in the refinement: 0.1603
• Goodness-of-fit parameter for all reflections included in the refinement: 0.992
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No