Information card for entry 4318375

Structure parameters

• Chemical name: [Pd(PP3)Cl]2(SnPh2Cl4).4H2O
• Formula: C48 H47 Cl3 O2 P4 Pd Sn0.5
• Calculated formula: C48 H47 Cl3 O2 P4 Pd Sn0.5
• Title of publication: Preparation and Structural Characterization of Ionic Five-Coordinate Palladium(II) and Platinum(II) Complexes of the Ligand Tris[2-(diphenylphosphino)ethyl]phosphine. Insertion of SnCl2 into M-Cl Bonds (M = Pd, Pt) and Hydroformylation Activity of the Pt-SnCl3 Systems
• Authors of publication: Damián Fernández; M. Inés García-Seijo; Tamás Kégl; György Petöcz; László Kollár; M. Esther García-Fernández
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 4435 - 4443
• a: 10.112 ± 0.002 Å
• b: 12.028 ± 0.003 Å
• c: 21.282 ± 0.005 Å
• α: 92.903 ± 0.004°
• β: 101.721 ± 0.004°
• γ: 111.854 ± 0.004°
• Cell volume: 2329.5 ± 0.9 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1379
• Residual factor for significantly intense reflections: 0.0566
• Weighted residual factors for significantly intense reflections: 0.1384
• Weighted residual factors for all reflections included in the refinement: 0.1637
• Goodness-of-fit parameter for all reflections included in the refinement: 0.958
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No