Information card for entry 4318794

Structure parameters

• Formula: C25 H35 B10 P2 Rh S
• Calculated formula: C25 H35 B10 P2 Rh S
• SMILES: [Rh]12345([P](C[P]([BH]([H]4)[H]5)(c4ccccc4)c4ccccc4)(c4ccccc4)c4ccccc4)[S]45[BH]671[BH]189[BH]%1046[BH]469[BH]9%118[BH]271[BH]139[BH]4%11([BH]5%106)[H]1
• Title of publication: Phosphine-Boranes as Bidentate Ligands: Formation of [8,8-η2-{η2-(BH3).dppm}-nido-8,7-RhSB9H10] and [9,9-η2-{η2-(BH3).dppm}-nido-9,7,8-RhC2B8H11] from [8,8-(η2-dppm)-8-(η1-dppm)-nido-8,7-RhSB9H10] and [9,9-(η2-dppm)-9-(η1-dppm)-nido-9,7,8-RhC2B8H11], Respectively
• Authors of publication: Oleg Volkov; Ramón Macías; Nigam P. Rath; Lawrence Barton
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 5837 - 5843
• a: 13.2721 ± 0.0001 Å
• b: 11.5727 ± 0.0001 Å
• c: 19.9181 ± 0.0002 Å
• α: 90°
• β: 94.898 ± 0.001°
• γ: 90°
• Cell volume: 3048.13 ± 0.05 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0469
• Residual factor for significantly intense reflections: 0.0303
• Weighted residual factors for all reflections: 0.0661
• Weighted residual factors for significantly intense reflections: 0.0597
• Goodness-of-fit parameter for all reflections: 1.045
• Goodness-of-fit parameter for significantly intense reflections: 1.067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No