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Information card for entry 4320055
Preview
Coordinates | 4320055.cif |
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Original paper (by DOI) | HTML |
Formula | C16 H42 B2 P2 |
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Calculated formula | C16 H42 B2 P2 |
SMILES | [P](C(C)(C)C)(C(C)(C)C)([BH2][PH](C(C)(C)C)C(C)(C)C)[BH3] |
Title of publication | Rhodium-Catalyzed Dehydrocoupling of the Sterically Encumbered Phosphine-Borane Adduct tBu2PH.BH3: Synthesis of the Linear Dimers tBu2PH-BH2-tBu2P-BH3 and tBu2PH-BH2-tBu2P-BH2Cl |
Authors of publication | Hendrik Dorn; Emira Vejzovic; Alan J. Lough; Ian Manners |
Journal of publication | Inorganic Chemistry |
Year of publication | 2001 |
Journal volume | 40 |
Pages of publication | 4327 - 4331 |
a | 8.885 ± 0.0002 Å |
b | 11.151 ± 0.0004 Å |
c | 11.339 ± 0.0004 Å |
α | 87.291 ± 0.0014° |
β | 76.992 ± 0.0016° |
γ | 70.411 ± 0.002° |
Cell volume | 1030.76 ± 0.06 Å3 |
Cell temperature | 150 ± 1 K |
Ambient diffraction temperature | 150 ± 1 K |
Number of distinct elements | 4 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0605 |
Residual factor for significantly intense reflections | 0.0396 |
Weighted residual factors for significantly intense reflections | 0.0891 |
Weighted residual factors for all reflections included in the refinement | 0.0975 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.055 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4320055.html
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