Information card for entry 4320056

Structure parameters

• Formula: C16 H41.21 B2 Cl0.79 P2
• Calculated formula: C16 H41.213 B2 Cl0.787 P2
• Title of publication: Rhodium-Catalyzed Dehydrocoupling of the Sterically Encumbered Phosphine-Borane Adduct tBu2PH.BH3: Synthesis of the Linear Dimers tBu2PH-BH2-tBu2P-BH3 and tBu2PH-BH2-tBu2P-BH2Cl
• Authors of publication: Hendrik Dorn; Emira Vejzovic; Alan J. Lough; Ian Manners
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 4327 - 4331
• a: 8.7446 ± 0.0003 Å
• b: 24.6411 ± 0.0009 Å
• c: 10.4574 ± 0.0005 Å
• α: 90°
• β: 101.857 ± 0.002°
• γ: 90°
• Cell volume: 2205.25 ± 0.15 ų
• Cell temperature: 240 ± 1 K
• Ambient diffraction temperature: 240 ± 1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0947
• Residual factor for significantly intense reflections: 0.0535
• Weighted residual factors for significantly intense reflections: 0.1222
• Weighted residual factors for all reflections included in the refinement: 0.1381
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No