Information card for entry 4321823

Structure parameters

• Chemical name: bis-(mu!2$-pyrazolate-N,N')-carbonyl-iodo-trimethylphosphite-rhodium(ii))
• Formula: C14 H24 I2 N4 O8 P2 Rh2
• Calculated formula: C14 H24 I2 N4 O8 P2 Rh2
• SMILES: [Rh]12([Rh](I)([P](OC)(OC)OC)([n]3n1ccc3)([n]1n2ccc1)C#[O])(I)([P](OC)(OC)OC)C#[O]
• Title of publication: Oxidative-Addition Reactions of Diiodine to Dinuclear Rhodium Pyrazolate Complexes
• Authors of publication: Cristina Tejel; Marta Bordonaba; Miguel A. Ciriano; Andrew J. Edwards; William Clegg; Fernando J. Lahoz; Luis A. Oro
• Journal of publication: Inorganic Chemistry
• Year of publication: 1999
• Journal volume: 38
• Pages of publication: 1108 - 1117
• a: 10.55 ± 0.002 Å
• b: 15.763 ± 0.003 Å
• c: 16.353 ± 0.003 Å
• α: 83.94 ± 0.03°
• β: 79.975 ± 0.015°
• γ: 83.97 ± 0.03°
• Cell volume: 2652.6 ± 0.9 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0834
• Residual factor for significantly intense reflections: 0.0494
• Weighted residual factors for significantly intense reflections: 0.104
• Weighted residual factors for all reflections included in the refinement: 0.118
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No