Information card for entry 4321824

Structure parameters

• Chemical name: (mu!2$-pyrazolate-N,N')-(mu!2$-carbonyl)-(carbonyl-iodo-tritolylphosphine rhodium(iii))-(iodo-tritolylphosphine-rhodium(iii)) diethylether solvate
• Formula: C52 H53 I2 N4 O2.5 P2 Rh2
• Calculated formula: C52 H53 I2 N4 O2.5 P2 Rh2
• Title of publication: Oxidative-Addition Reactions of Diiodine to Dinuclear Rhodium Pyrazolate Complexes
• Authors of publication: Cristina Tejel; Marta Bordonaba; Miguel A. Ciriano; Andrew J. Edwards; William Clegg; Fernando J. Lahoz; Luis A. Oro
• Journal of publication: Inorganic Chemistry
• Year of publication: 1999
• Journal volume: 38
• Pages of publication: 1108 - 1117
• a: 11.3869 ± 0.0009 Å
• b: 16.2642 ± 0.0013 Å
• c: 16.5072 ± 0.0014 Å
• α: 95.34 ± 0.002°
• β: 96.41 ± 0.002°
• γ: 110.191 ± 0.002°
• Cell volume: 2822.8 ± 0.4 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0885
• Residual factor for significantly intense reflections: 0.0504
• Weighted residual factors for significantly intense reflections: 0.1131
• Weighted residual factors for all reflections included in the refinement: 0.1289
• Goodness-of-fit parameter for all reflections included in the refinement: 1.019
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No