Information card for entry 4323317

Structure parameters

• Common name: cis,cis-Tetrachloro-bis(diethylamido)-bis(diethylamine) ditungsten(III)
• Chemical name: 1,1,2,2-Tetrachloro-1,2-bis(diethylamido)-(cis,cis)-1,2- bis(diethylamine) ditungsten(III)
• Formula: C16 H42 Cl4 N4 W2
• Calculated formula: C16 H42 Cl4 N4 W2
• Title of publication: W2Cl4(NR2)2(PR'3)2 Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and Characterizations of W2Cl4(NR2)2(PR'3)2 (R = Et, Bu, Hex; R'3= Me3, Et2H) and an Intermediate Complex W2Cl4(NEt2)2(NHEt2)2
• Authors of publication: F. Albert Cotton; Evgeny V. Dikarev; N. Nawar; Wai-Yeung Wong
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 559 - 566
• a: 11.6704 ± 0.0009 Å
• b: 13.336 ± 0.001 Å
• c: 17.321 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2695.8 ± 0.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 45
• Hermann-Mauguin space group symbol: I b a 2
• Hall space group symbol: I 2 -2c
• Residual factor for all reflections: 0.0282
• Residual factor for significantly intense reflections: 0.0224
• Weighted residual factors for all reflections: 0.056
• Weighted residual factors for significantly intense reflections: 0.0539
• Goodness-of-fit parameter for all reflections: 1.098
• Goodness-of-fit parameter for significantly intense reflections: 1.101
• Diffraction radiation wavelength: 0.7093 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No