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Information card for entry 4323468
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Coordinates | 4323468.cif |
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Original paper (by DOI) | HTML |
Common name | cis,cis-Tetrachloro-bis(n-propylamido)- bis(trimethylphosphine) ditungsten(III) |
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Chemical name | 1,1,2,2-Tetrachloro-1,2-bis(n-propylamido)-(cis,cis)- 1,2-bis(trimethylphosphine)ditungsten(III) |
Formula | C12 H34 Cl4 N2 P2 W2 |
Calculated formula | C12 H34 Cl4 N2 P2 W2 |
Title of publication | W2Cl4(NR2)2(PR'3)2 Molecules. 8. Synthesis and Structural Characterization of Both Cis Isomers of Stoichiometry W2Cl4(NHR)2(PMe3)2, R = Et, Prn, and Bun. Direct Evidence Favoring an Internal Flip Mechanism for Cis-Trans Isomerization |
Authors of publication | F. Albert Cotton; Evgeny V. Dikarev; Wai-Yeung Wong |
Journal of publication | Inorganic Chemistry |
Year of publication | 1997 |
Journal volume | 36 |
Pages of publication | 2670 - 2677 |
a | 13.1268 ± 0.0008 Å |
b | 10.871 ± 0.001 Å |
c | 17.106 ± 0.001 Å |
α | 90° |
β | 92.872 ± 0.005° |
γ | 90° |
Cell volume | 2438 ± 0.3 Å3 |
Cell temperature | 213 ± 2 K |
Ambient diffraction temperature | 213 ± 2 K |
Number of distinct elements | 6 |
Space group number | 15 |
Hermann-Mauguin space group symbol | I 1 2/a 1 |
Hall space group symbol | -I 2ya |
Residual factor for all reflections | 0.0445 |
Residual factor for significantly intense reflections | 0.038 |
Weighted residual factors for all reflections | 0.0933 |
Weighted residual factors for significantly intense reflections | 0.0894 |
Goodness-of-fit parameter for all reflections | 1.086 |
Goodness-of-fit parameter for significantly intense reflections | 1.108 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
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