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Information card for entry 4323469
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Coordinates | 4323469.cif |
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Original paper (by DOI) | HTML |
Common name | cis,cis-Tetrachloro-bis(n-butylamido)- bis(trimethylphosphine) ditungsten(III) |
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Chemical name | 1,1,2,2-Tetrachloro-1,2-bis(n-butylamido)-(cis,cis)- 1,2-bis(trimethylphosphine)ditungsten(III) |
Formula | C14 H38 Cl4 N2 P2 W2 |
Calculated formula | C14 H38 Cl4 N2 P2 W2 |
Title of publication | W2Cl4(NR2)2(PR'3)2 Molecules. 8. Synthesis and Structural Characterization of Both Cis Isomers of Stoichiometry W2Cl4(NHR)2(PMe3)2, R = Et, Prn, and Bun. Direct Evidence Favoring an Internal Flip Mechanism for Cis-Trans Isomerization |
Authors of publication | F. Albert Cotton; Evgeny V. Dikarev; Wai-Yeung Wong |
Journal of publication | Inorganic Chemistry |
Year of publication | 1997 |
Journal volume | 36 |
Pages of publication | 2670 - 2677 |
a | 22.058 ± 0.009 Å |
b | 8.562 ± 0.001 Å |
c | 29.768 ± 0.008 Å |
α | 90° |
β | 105.642 ± 0.001° |
γ | 90° |
Cell volume | 5414 ± 3 Å3 |
Cell temperature | 213 ± 2 K |
Ambient diffraction temperature | 213 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.1181 |
Residual factor for significantly intense reflections | 0.0603 |
Weighted residual factors for all reflections | 0.1532 |
Weighted residual factors for significantly intense reflections | 0.1321 |
Goodness-of-fit parameter for all reflections | 0.939 |
Goodness-of-fit parameter for significantly intense reflections | 1.097 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
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