Information card for entry 4324049

Structure parameters

• Common name: 1,3,6-ditechnetium pentachloro tris(dimethylphenylphosphine)
• Chemical name: 1,3,6-ditechnetium pentachloro tris(dimethylphenylphosphine)
• Formula: C24 H33 Cl5 P3 Tc2
• Calculated formula: C24 H33 Cl5 P3 Tc1.9994
• Title of publication: Metal-Metal Multiply-Bonded Complexes of Technetium. 3.1 Preparation and Characterization of Phosphine Complexes of Technetium Possessing a Metal-Metal Bond Order of 3.5
• Authors of publication: F. Albert Cotton; Steven C. Haefner; Alfred P. Sattelberger
• Journal of publication: Inorganic Chemistry
• Year of publication: 1996
• Journal volume: 35
• Pages of publication: 1831 - 1838
• a: 11.134 ± 0.0014 Å
• b: 14.4057 ± 0.0013 Å
• c: 19.501 ± 0.003 Å
• α: 90°
• β: 98.144 ± 0.006°
• γ: 90°
• Cell volume: 3096.3 ± 0.7 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0435
• Residual factor for significantly intense reflections: 0.0261
• Weighted residual factors for all reflections: 0.0806
• Weighted residual factors for significantly intense reflections: 0.0659
• Goodness-of-fit parameter for all reflections: 1.103
• Goodness-of-fit parameter for significantly intense reflections: 1.067
• Diffraction radiation wavelength: 0.7093 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No