Information card for entry 4324729

Structure parameters

• Chemical name: N,N',N'-tris(trimethylsilyl)hydrazino-methyl(phenyl)phosphane galliumtrichloride addukt
• Formula: C16 H35 Cl3 Ga N2 P Si3
• Calculated formula: C16 H35 Cl3 Ga N2 P Si3
• SMILES: [Ga](Cl)(Cl)(Cl)[P](N(N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C)(C)c1ccccc1
• Title of publication: Lewis Acid Assisted Methyl/Chlorine Exchange in Silylated Hydrazinochlorophosphanes
• Authors of publication: Andrea Westenkirchner; Alexander Villinger; Konstantin Karaghiosoff; Ronald Wustrack; Dirk Michalik; Axel Schulz
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 2691 - 2702
• a: 9.8091 ± 0.0003 Å
• b: 15.7487 ± 0.0005 Å
• c: 17.4956 ± 0.0006 Å
• α: 90°
• β: 99.759 ± 0.002°
• γ: 90°
• Cell volume: 2663.62 ± 0.15 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0417
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.0775
• Weighted residual factors for all reflections included in the refinement: 0.082
• Goodness-of-fit parameter for all reflections included in the refinement: 1.069
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No