Information card for entry 4324728

Structure parameters

• Chemical name: N,N',N'-tris(trimethylsilyl)hydrazino-methyl(chloro)phosphane Galliumtrichloride addukt
• Formula: C10 H30 Cl4 Ga N2 P Si3
• Calculated formula: C10 H30 Cl4 Ga N2 P Si3
• SMILES: [Ga]([P@](N([Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)(Cl)C)(Cl)(Cl)Cl
• Title of publication: Lewis Acid Assisted Methyl/Chlorine Exchange in Silylated Hydrazinochlorophosphanes
• Authors of publication: Andrea Westenkirchner; Alexander Villinger; Konstantin Karaghiosoff; Ronald Wustrack; Dirk Michalik; Axel Schulz
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 2691 - 2702
• a: 8.5157 ± 0.0002 Å
• b: 12.6961 ± 0.0004 Å
• c: 11.001 ± 0.0003 Å
• α: 90°
• β: 99.679 ± 0.001°
• γ: 90°
• Cell volume: 1172.46 ± 0.06 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0192
• Residual factor for significantly intense reflections: 0.0177
• Weighted residual factors for significantly intense reflections: 0.0459
• Weighted residual factors for all reflections included in the refinement: 0.0464
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No