Information card for entry 4325120

Structure parameters

• Chemical name: Lithium Manganese(III) tetrakis(bistert-butyl ketimide)
• Formula: C36 H72 Li Mn N4
• Calculated formula: C36 H72 Li Mn N4
• Title of publication: Stabilizing High-Valent Metal Ions with a Ketimide Ligand Set: Synthesis of Mn(N=CtBu2)4
• Authors of publication: Richard A. Lewis; Guang Wu; Trevor W. Hayton
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 4660 - 4668
• a: 16.7762 ± 0.0012 Å
• b: 15.2054 ± 0.001 Å
• c: 15.8446 ± 0.0011 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4041.8 ± 0.5 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 52
• Hermann-Mauguin space group symbol: P n n a
• Hall space group symbol: -P 2a 2bc
• Residual factor for all reflections: 0.1033
• Residual factor for significantly intense reflections: 0.0641
• Weighted residual factors for significantly intense reflections: 0.1655
• Weighted residual factors for all reflections included in the refinement: 0.1999
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No