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Information card for entry 4325121
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Coordinates | 4325121.cif |
---|---|
Original paper (by DOI) | HTML |
Chemical name | [Lithium di(1,4,7,10-tetraoxacyclododecane)] Manganese(III) tetrakis(bistert-butyl ketimide) |
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Formula | C52 H104 Li Mn N4 O8 |
Calculated formula | C52 H104 Li Mn N4 O8 |
SMILES | [Mn](N=C(C(C)(C)C)C(C)(C)C)(N=C(C(C)(C)C)C(C)(C)C)(N=C(C(C)(C)C)C(C)(C)C)N=C(C(C)(C)C)C(C)(C)C.[O]12CC[O]3CC[O]4CC[O](CC1)[Li]156234[O]2CC[O]6CC[O]1CC[O]5CC2 |
Title of publication | Stabilizing High-Valent Metal Ions with a Ketimide Ligand Set: Synthesis of Mn(N=CtBu2)4 |
Authors of publication | Richard A. Lewis; Guang Wu; Trevor W. Hayton |
Journal of publication | Inorganic Chemistry |
Year of publication | 2011 |
Journal volume | 50 |
Pages of publication | 4660 - 4668 |
a | 13.611 ± 0.003 Å |
b | 13.612 ± 0.003 Å |
c | 16.36 ± 0.004 Å |
α | 105.791 ± 0.005° |
β | 92.476 ± 0.005° |
γ | 90.013 ± 0.005° |
Cell volume | 2913.7 ± 1.2 Å3 |
Cell temperature | 150 ± 2 K |
Ambient diffraction temperature | 150 ± 2 K |
Number of distinct elements | 6 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.1654 |
Residual factor for significantly intense reflections | 0.0678 |
Weighted residual factors for significantly intense reflections | 0.141 |
Weighted residual factors for all reflections included in the refinement | 0.1781 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.93 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4325121.html
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