Information card for entry 4325238

Structure parameters

• Chemical name: Triphenylmonoiodophosphonium Uranium(V) tetraiodo-bistrimethylsilyloxide
• Formula: C24 H33 I5 O2 P Si2 U
• Calculated formula: C24 H33 I5 O2 P Si2 U
• Title of publication: Facile Reduction of a Uranyl(VI) β-Ketoiminate Complex to U(IV) Upon Oxo Silylation
• Authors of publication: Jessie L. Brown; Charles C. Mokhtarzadeh; Jeremie M. Lever; Guang Wu; Trevor W. Hayton
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 5105 - 5112
• a: 9.452 ± 0.007 Å
• b: 9.961 ± 0.008 Å
• c: 20.94 ± 0.016 Å
• α: 103.327 ± 0.012°
• β: 90.511 ± 0.013°
• γ: 101.222 ± 0.012°
• Cell volume: 1879 ± 3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0654
• Residual factor for significantly intense reflections: 0.0494
• Weighted residual factors for significantly intense reflections: 0.1216
• Weighted residual factors for all reflections included in the refinement: 0.1346
• Goodness-of-fit parameter for all reflections included in the refinement: 1.004
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No