Information card for entry 4325239

Structure parameters

• Chemical name: Uranium(IV) bis(bipryridine)bis(iodo)bis(trimethylsilyloxide)
• Formula: C27 H34 Cl2 I2 N4 O2 Si2 U
• Calculated formula: C27 H34 Cl2 I2 N4 O2 Si2 U
• Title of publication: Facile Reduction of a Uranyl(VI) β-Ketoiminate Complex to U(IV) Upon Oxo Silylation
• Authors of publication: Jessie L. Brown; Charles C. Mokhtarzadeh; Jeremie M. Lever; Guang Wu; Trevor W. Hayton
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 5105 - 5112
• a: 20.377 ± 0.007 Å
• b: 9.122 ± 0.003 Å
• c: 19.007 ± 0.006 Å
• α: 90°
• β: 90.883 ± 0.006°
• γ: 90°
• Cell volume: 3533 ± 2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.056
• Residual factor for significantly intense reflections: 0.0389
• Weighted residual factors for significantly intense reflections: 0.0892
• Weighted residual factors for all reflections included in the refinement: 0.0962
• Goodness-of-fit parameter for all reflections included in the refinement: 1.088
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No