Information card for entry 4326255

Structure parameters

• Formula: C47 H47 F18 N10 O3 Os2 P3
• Calculated formula: C47 H47 F18 N10 O3 Os2 P3
• SMILES: [Os]1234(O[Os]567([O]=C(O1)c1ccccc1)[N](Cc1[n]5cccc1)(Cc1[n]6cccc1)Cc1[n]7cccc1)[N](Cc1[n]2cccc1)(Cc1[n]3cccc1)Cc1[n]4cccc1.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].N#CC.N#CC
• Title of publication: Synthesis and Properties of Oxo-carboxylato- and Dioxo-Bridged Diosmium Complexes of Tris(2-pyridylmethyl)amine
• Authors of publication: Hideki Sugimoto; Kazuhiro Kitayama; Kenji Ashikari; Chikako Matsunami; Naomi Ueda; Keisuke Umakoshi; Yuko Hosokoshi; Yoichi Sasaki; Shinobu Itoh
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 9014 - 9023
• a: 12.0808 ± 0.0012 Å
• b: 19.319 ± 0.0018 Å
• c: 23.521 ± 0.002 Å
• α: 90°
• β: 100.427 ± 0.001°
• γ: 90°
• Cell volume: 5398.9 ± 0.9 ų
• Cell temperature: 113.1 K
• Ambient diffraction temperature: 113 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0365
• Weighted residual factors for all reflections included in the refinement: 0.1568
• Goodness-of-fit parameter for all reflections included in the refinement: 0.656
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No