Information card for entry 4327672

Structure parameters

• Formula: C49 H30 N O13 P2 Rh Ru3
• Calculated formula: C49 H30 N O13 P2 Rh Ru3
• SMILES: [Rh]12345([Ru]6([Ru]1([Ru]26(C#[O])(C#[O])(C#[O])C5=O)(C#[O])(C#[O])(C#[O])C4=O)(C#[O])(C#[O])(C#[O])C3=O)C#[O].P(=N[P+](c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Mixed Ruthenium-Rhodium Carbonyl Cluster Complexes. Synthesis of the Anions [Ru3Rh(CO)13]- and [RuRh3(CO)12]- and Crystal Structures of Their [N(PPh3)2]+ Salts 1
• Authors of publication: Alessandro Fumagalli; Mascia Bianchi; Maria Carlotta Malatesta; Gianfranco Ciani; Massimo Moret; Angelo Sironi
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 1324 - 1328
• a: 9.827 ± 0.002 Å
• b: 14.911 ± 0.002 Å
• c: 18.735 ± 0.003 Å
• α: 110.53 ± 0.01°
• β: 99.79 ± 0.02°
• γ: 91.85 ± 0.02°
• Cell volume: 2520.9 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0347
• Residual factor for significantly intense reflections: 0.0342
• Weighted residual factors for all reflections: 0.0983
• Weighted residual factors for significantly intense reflections: 0.0926
• Goodness-of-fit parameter for all reflections: 1.026
• Goodness-of-fit parameter for significantly intense reflections: 1.026
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No