Information card for entry 4327673

Structure parameters

• Formula: C48 H30 N O12 P2 Rh3 Ru
• Calculated formula: C48 H30 N O12 P2 Rh3 Ru
• SMILES: [Ru]1234([Rh]567([Rh]81([Rh]25(C#[O])(C#[O])(C7=O)C8=O)(C#[O])(C4=O)C6=O)(C#[O])C3=O)(C#[O])(C#[O])C#[O].P(=N[P+](c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Mixed Ruthenium-Rhodium Carbonyl Cluster Complexes. Synthesis of the Anions [Ru3Rh(CO)13]- and [RuRh3(CO)12]- and Crystal Structures of Their [N(PPh3)2]+ Salts 1
• Authors of publication: Alessandro Fumagalli; Mascia Bianchi; Maria Carlotta Malatesta; Gianfranco Ciani; Massimo Moret; Angelo Sironi
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 1324 - 1328
• a: 14.746 ± 0.003 Å
• b: 21.395 ± 0.004 Å
• c: 16.14 ± 0.004 Å
• α: 90°
• β: 102.95 ± 0.02°
• γ: 90°
• Cell volume: 4962.5 ± 1.9 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0582
• Residual factor for significantly intense reflections: 0.0582
• Weighted residual factors for all reflections: 0.1389
• Weighted residual factors for significantly intense reflections: 0.1383
• Goodness-of-fit parameter for all reflections: 1.079
• Goodness-of-fit parameter for significantly intense reflections: 1.079
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No