Information card for entry 4327967

Structure parameters

• Formula: C80 H78 Co2 N2 O2 P6
• Calculated formula: C80 H78 Co2 N2 O2 P6
• Title of publication: The Intramolecular Rearrangement of Phosphinohydrazides [R'2P-NR-NR-M] →[RN=PR'2-NR-M]: General Rules and Exceptions. Transformations of Bulky Phosphinohydrazines (R-NH-N(PPh2)2, R =tBu, Ph2P)
• Authors of publication: Alexander N. Kornev; Vyacheslav V. Sushev; Yulia S. Panova; Natalia V. Belina; Olga V. Lukoyanova; Georgy K. Fukin; Sergey Y. Ketkov; Gleb A. Abakumov; Peter Lönnecke; Evamarie Hey-Hawkins
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 874 - 881
• a: 16.1309 ± 0.0008 Å
• b: 21.1279 ± 0.001 Å
• c: 19.9712 ± 0.0009 Å
• α: 90°
• β: 94.437 ± 0.001°
• γ: 90°
• Cell volume: 6786 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1202
• Residual factor for significantly intense reflections: 0.0595
• Weighted residual factors for significantly intense reflections: 0.0956
• Weighted residual factors for all reflections included in the refinement: 0.1075
• Goodness-of-fit parameter for all reflections included in the refinement: 0.997
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No