Information card for entry 4329835

Structure parameters

• Chemical name: N-azidodimethylsilyl-N-[2,6-bis(2,4,6-trimethylphenyl)phenyl]amino-chloro- methylstibane
• Formula: C27 H34 Cl N4 Sb Si
• Calculated formula: C27 H34 Cl N4 Sb Si
• SMILES: [Sb](Cl)(N([Si](N=N#N)(C)C)c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)C
• Title of publication: Chlorine/Methyl Exchange Reactions in Silylated Aminostibanes: A New Route To Stibinostibonium Cations
• Authors of publication: Christian Hering; Mathias Lehmann; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 8212 - 8224
• a: 10.7029 ± 0.0004 Å
• b: 15.7205 ± 0.0006 Å
• c: 16.4317 ± 0.0006 Å
• α: 90°
• β: 95.279 ± 0.002°
• γ: 90°
• Cell volume: 2752.99 ± 0.18 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0374
• Residual factor for significantly intense reflections: 0.0259
• Weighted residual factors for significantly intense reflections: 0.0656
• Weighted residual factors for all reflections included in the refinement: 0.0689
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No