Information card for entry 4330134

Structure parameters

• Formula: C132 H148 Au4 N2 O20 P4 Rh10
• Calculated formula: C132 H148 Au4 N2 O20 P4 Rh10
• SMILES: [C]12345[Rh]6789%10%11%12%13%14(C#[O])[Rh]%15%16%171(C#[O])C(=O)[Rh]1%18%19%2026%15(C#[O])[Au]2([P](c6ccccc6)(c6ccccc6)c6ccccc6)[Rh]6%15%21%22%23%243%10%19([C]3%10%197[Rh]7%25%26%11(C#[O])C(=O)[Rh]%11%132%23%10%25(C#[O])([Au]91[P](c1ccccc1)(c1ccccc1)c1ccccc1)C(=O)[Rh]1%213%11(C#[O])C(=O)[Rh]2%14%24%19%261(C#[O])([Au]8([P](c1ccccc1)(c1ccccc1)c1ccccc1)[Rh]15%12%17%22(C#[O])([Au]62[P](c2ccccc2)(c2ccccc2)c2ccccc2)(C(=O)[Rh]4%20%151(C#[O])C%18=O)C%16=O)C7=O)C#[O].[N+](CCCC)(CCCC)(CCCC)CCCC.C1CCCO1.[N+](CCCC)(CCCC)(CCCC)CCCC.C1CCCO1
• Title of publication: Synthesis, Reactivity, Electrochemical Behavior, and Crystal Structure of a Family of Multivalent Metal Carbido-Carbonyl Clusters Based on the Rh10(C)2Au4-6Framework
• Authors of publication: Laura Cherchi; Alessandro Fumagalli; Serena Fedi; Piero Zanello; Fabrizia Fabrizi De Biani; Franco Laschi; Luigi Garlaschelli; Piero Macchi; Angelo Sironi
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 9171 - 9180
• a: 15.675 ± 0.003 Å
• b: 27.297 ± 0.005 Å
• c: 17.166 ± 0.003 Å
• α: 90°
• β: 113.049 ± 0.002°
• γ: 90°
• Cell volume: 6759 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0679
• Residual factor for significantly intense reflections: 0.036
• Weighted residual factors for significantly intense reflections: 0.0588
• Weighted residual factors for all reflections included in the refinement: 0.0674
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No