Information card for entry 4333618

Structure parameters

• Formula: Co2 H86 K5 Na7 O109 Si2 W18
• Calculated formula: Co2 K5 Na7 O87.75 Si2 W18
• SMILES: [Co]12([O]34[Si]56[O]78[W]9%10%11(=O)O[W]%12%137(=O)O[W]78(=O)(O9)O[W]83(=O)(O[W]3(=O)(O[W](O%10)(=O)(O[W]9%10(O%11)(=O)O[W](O%12)(=O)(O[W]4(O%13)(=O)(O8)=[O]1)([O]59)O[W]145([O]8[Si]9%11[O]%12[W]%13%14(=O)(O[W]%15%16%17(=[O][Co]%18([OH2])([OH2])[O]=[W]%19([O]9%15%18)(O%16)(=O)O[W]8(O%10)(=O)(O1)O[W]18([O]9%11[W](O5)(O[W]%12(O4)(=O)(=O)O%13)(=O)(O1)O[W]9(O%14)(=O)(O8)O%17)(O%19)=O)=O)=O)=O)([O]63)=O)(O7)=O)=[O]2)([OH2])([OH2])[OH2].[K+].O.[K+].[K+].[K+].[Na+].[K+].O.[Na+].[Na+].[Na+].O.[Na+].O.[Na+].O.[Na+].O.O.O.O.O.O.O.O.O.O.O.O
• Title of publication: Di- and Tri-Cobalt Silicotungstates: Synthesis, Characterization, and Stability Studies
• Authors of publication: Guibo Zhu; Yurii V. Geletii; Jie Song; Chongchao Zhao; Elliot N. Glass; John Bacsa; Craig L. Hill
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 1018 - 1024
• a: 12.846 ± 0.005 Å
• b: 18.671 ± 0.007 Å
• c: 20.889 ± 0.007 Å
• α: 69.166 ± 0.005°
• β: 87.147 ± 0.006°
• γ: 81.561 ± 0.006°
• Cell volume: 4632 ± 3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0681
• Residual factor for significantly intense reflections: 0.0524
• Weighted residual factors for significantly intense reflections: 0.143
• Weighted residual factors for all reflections included in the refinement: 0.152
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No