Information card for entry 4334676

Structure parameters

• Chemical name: N,N-bis(trimethylsilyl)amino(isothiocyanato)phosphenium tetrachlorogallate
• Formula: C7 H18 Cl4 Ga N2 P S Si2
• Calculated formula: C7 H18 Cl4 Ga N2 P S Si2
• Title of publication: On the Synthesis and Reactivity of Highly Labile Pseudohalogen Phosphenium Ions
• Authors of publication: Christian Hering; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 5214 - 5225
• a: 12.6909 ± 0.0005 Å
• b: 16.7821 ± 0.0007 Å
• c: 18.7192 ± 0.0007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3986.8 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0719
• Residual factor for significantly intense reflections: 0.0333
• Weighted residual factors for significantly intense reflections: 0.0654
• Weighted residual factors for all reflections included in the refinement: 0.0723
• Goodness-of-fit parameter for all reflections included in the refinement: 1.004
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No