Information card for entry 4334678

Structure parameters

• Chemical name: N,N-bis(trimethylsilyl)amino(trimethylsiloxy)phosphenium tetrachlorogallate
• Formula: C9 H27 Cl4 Ga N O P Si3
• Calculated formula: C9 H27 Cl4 Ga N O P Si3
• Title of publication: On the Synthesis and Reactivity of Highly Labile Pseudohalogen Phosphenium Ions
• Authors of publication: Christian Hering; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 5214 - 5225
• a: 11.9101 ± 0.0006 Å
• b: 11.8333 ± 0.0006 Å
• c: 16.849 ± 0.0009 Å
• α: 90°
• β: 98.97 ± 0.002°
• γ: 90°
• Cell volume: 2345.6 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0877
• Residual factor for significantly intense reflections: 0.0437
• Weighted residual factors for significantly intense reflections: 0.0876
• Weighted residual factors for all reflections included in the refinement: 0.0969
• Goodness-of-fit parameter for all reflections included in the refinement: 0.956
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No