Information card for entry 4334679

Structure parameters

• Chemical name: N,N-bis(trimethylsilyl)amino(4-dimethylaminopyridyl)chlorophosphenium tetrachlorogallate
• Formula: C13 H28 Cl5 Ga N3 P Si2
• Calculated formula: C13 H28 Cl5 Ga N3 P Si2
• SMILES: P(Cl)(N([Si](C)(C)C)[Si](C)(C)C)[n+]1ccc(N(C)C)cc1.[Ga](Cl)([Cl-])(Cl)Cl
• Title of publication: On the Synthesis and Reactivity of Highly Labile Pseudohalogen Phosphenium Ions
• Authors of publication: Christian Hering; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 5214 - 5225
• a: 14.6109 ± 0.001 Å
• b: 9.8655 ± 0.0007 Å
• c: 18.3744 ± 0.0013 Å
• α: 90°
• β: 108.271 ± 0.002°
• γ: 90°
• Cell volume: 2515 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0569
• Residual factor for significantly intense reflections: 0.0324
• Weighted residual factors for significantly intense reflections: 0.0755
• Weighted residual factors for all reflections included in the refinement: 0.0813
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No