Information card for entry 4334681

Structure parameters

• Chemical name: N,N-bis(trimethylsilyl)amino(4-dimethylaminopyridyl)isocyanatophosphenium tetrachlorogallate
• Formula: C13.9 H28 Cl4.1 Ga N3.9 O0.9 P Si2
• Calculated formula: C13.902 H28 Cl4.098 Ga N3.902 O0.902 P Si2
• Title of publication: On the Synthesis and Reactivity of Highly Labile Pseudohalogen Phosphenium Ions
• Authors of publication: Christian Hering; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 5214 - 5225
• a: 15.5311 ± 0.0008 Å
• b: 9.3799 ± 0.0005 Å
• c: 18.6699 ± 0.0011 Å
• α: 90°
• β: 111.377 ± 0.003°
• γ: 90°
• Cell volume: 2532.7 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0935
• Residual factor for significantly intense reflections: 0.0403
• Weighted residual factors for significantly intense reflections: 0.0838
• Weighted residual factors for all reflections included in the refinement: 0.0939
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No