Information card for entry 4334682

Structure parameters

• Formula: C12 H28 Cl5 Ga N P Si2
• Calculated formula: C12 H28 Cl5 Ga N P Si2
• SMILES: [P+]1(Cl)(N([Si](C)(C)C)[Si](C)(C)C)CC(=C(C1)C)C.[Ga](Cl)(Cl)(Cl)[Cl-]
• Title of publication: On the Synthesis and Reactivity of Highly Labile Pseudohalogen Phosphenium Ions
• Authors of publication: Christian Hering; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 5214 - 5225
• a: 15.8188 ± 0.0002 Å
• b: 10.8989 ± 0.0001 Å
• c: 14.8901 ± 0.0002 Å
• α: 90°
• β: 114.68 ± 0.001°
• γ: 90°
• Cell volume: 2332.66 ± 0.05 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.035
• Residual factor for significantly intense reflections: 0.0245
• Weighted residual factors for significantly intense reflections: 0.058
• Weighted residual factors for all reflections included in the refinement: 0.0619
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No