Information card for entry 4335572

Structure parameters

• Formula: H248 Na32.5 Ni14 O365 P12 Rb1.5 W60
• Calculated formula: Na9.9 Ni14 O297.5 P12 Rb0.25 W60
• Title of publication: Synthesis, Magnetism, and Electrochemistry of the Ni14- and Ni5-Containing Heteropolytungstates [Ni14(OH)6(H2O)10(HPO4)4(P2W15O56)4]34- and [Ni5(OH)4(H2O)4(β-GeW9O34)(β-GeW8O30(OH))]13-
• Authors of publication: Masooma Ibrahim; Yixian Xiang; Bassem S. Bassil; Yanhua Lan; Annie K. Powell; Pedro de Oliveira; Bineta Keita; Ulrich Kortz
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 8399 - 8408
• a: 15.6062 ± 0.0005 Å
• b: 24.9652 ± 0.0009 Å
• c: 49.49 ± 0.002 Å
• α: 90.601 ± 0.003°
• β: 92.688 ± 0.002°
• γ: 90.439 ± 0.002°
• Cell volume: 19259 ± 1.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1807
• Residual factor for significantly intense reflections: 0.1067
• Weighted residual factors for significantly intense reflections: 0.2262
• Weighted residual factors for all reflections included in the refinement: 0.2772
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No