Information card for entry 4339420

Structure parameters

• Formula: C30 H62 Co N2 P2 Si2
• Calculated formula: C30 H62 Co N2 P2 Si2
• SMILES: [Co]12([P](C[Si](N2[Si](C)(C)C[P]1(C(C)(C)C)C(C)(C)C)(C)C)(C(C)(C)C)C(C)(C)C)Nc1c(cccc1C)C
• Title of publication: Exploring the reactivity of four-coordinate PNPCoX with access to three-coordinate spin triplet PNPCo.
• Authors of publication: Ingleson, Michael J.; Pink, Maren; Fan, Hongjun; Caulton, Kenneth G.
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 24
• Pages of publication: 10321 - 10334
• a: 16.842 ± 0.004 Å
• b: 10.587 ± 0.002 Å
• c: 20.98 ± 0.005 Å
• α: 90°
• β: 107.7 ± 0.006°
• γ: 90°
• Cell volume: 3563.8 ± 1.4 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0797
• Residual factor for significantly intense reflections: 0.0421
• Weighted residual factors for significantly intense reflections: 0.0891
• Weighted residual factors for all reflections included in the refinement: 0.1032
• Goodness-of-fit parameter for all reflections included in the refinement: 0.998
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No