Information card for entry 4339422

Structure parameters

• Formula: C22 H52 Co I N P2 Si2
• Calculated formula: C22 H52 Co I N P2 Si2
• SMILES: I[Co]12[P](C[Si](N2[Si](C)(C)C[P]1(C(C)(C)C)C(C)(C)C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Exploring the reactivity of four-coordinate PNPCoX with access to three-coordinate spin triplet PNPCo.
• Authors of publication: Ingleson, Michael J.; Pink, Maren; Fan, Hongjun; Caulton, Kenneth G.
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 24
• Pages of publication: 10321 - 10334
• a: 11.415 ± 0.0012 Å
• b: 15.151 ± 0.0016 Å
• c: 18.1427 ± 0.0019 Å
• α: 90°
• β: 101.281 ± 0.003°
• γ: 90°
• Cell volume: 3077.1 ± 0.6 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0246
• Residual factor for significantly intense reflections: 0.0211
• Weighted residual factors for significantly intense reflections: 0.0507
• Weighted residual factors for all reflections included in the refinement: 0.053
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No