Information card for entry 4341287

Structure parameters

• Formula: C59 H72 Cl2 Mo4 O12 P6 W2
• Calculated formula: C59 H72 Cl2 Mo4 O12 P6 W2
• Title of publication: Mild P-P Bond Cleavage in the Methyldiphosphenyl Complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] To Give Novel Phosphide-Bridged Trinuclear Derivatives.
• Authors of publication: Alvarez, M. Angeles; García, M Esther; García-Vivó, Daniel; Lozano, Raquel; Ramos, Alberto; Ruiz, Miguel A.
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 20
• Pages of publication: 11261 - 11273
• a: 11.458 ± 0.005 Å
• b: 18.27 ± 0.005 Å
• c: 18.747 ± 0.005 Å
• α: 111.258 ± 0.005°
• β: 99.502 ± 0.005°
• γ: 106.801 ± 0.005°
• Cell volume: 3337.3 ± 1.9 ų
• Cell temperature: 124 ± 3 K
• Ambient diffraction temperature: 124 ± 3 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0399
• Residual factor for significantly intense reflections: 0.0328
• Weighted residual factors for significantly intense reflections: 0.0802
• Weighted residual factors for all reflections included in the refinement: 0.0855
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No