Information card for entry 4341288

Structure parameters

• Formula: C29 H32 Mo2 O7 P2 W
• Calculated formula: C29 H32 Mo2 O7 P2 W
• Title of publication: Mild P-P Bond Cleavage in the Methyldiphosphenyl Complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] To Give Novel Phosphide-Bridged Trinuclear Derivatives.
• Authors of publication: Alvarez, M. Angeles; García, M Esther; García-Vivó, Daniel; Lozano, Raquel; Ramos, Alberto; Ruiz, Miguel A.
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 20
• Pages of publication: 11261 - 11273
• a: 10.4478 ± 0.0008 Å
• b: 11.2943 ± 0.0012 Å
• c: 14.2992 ± 0.0017 Å
• α: 71.451 ± 0.011°
• β: 88.166 ± 0.008°
• γ: 83.909 ± 0.008°
• Cell volume: 1590.6 ± 0.3 ų
• Cell temperature: 123 ± 0.14 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1221
• Residual factor for significantly intense reflections: 0.0695
• Weighted residual factors for significantly intense reflections: 0.1673
• Weighted residual factors for all reflections included in the refinement: 0.2121
• Goodness-of-fit parameter for all reflections included in the refinement: 0.954
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No