Information card for entry 4342606

Structure parameters

• Formula: C50 H90 B N3 O2 Si6 U
• Calculated formula: C50 H90 B N3 O2 Si6 U
• SMILES: [U]([O]1CCCC1)(N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C.O1CCCC1.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: U(III)-CN versus U(IV)-NC Coordination in Tris(silylamide) Complexes.
• Authors of publication: Hervé, Alexandre; Bouzidi, Yamina; Berthet, Jean-Claude; Belkhiri, Lotfi; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 5
• Pages of publication: 2474
• a: 16.9269 ± 0.0007 Å
• b: 18.7867 ± 0.0006 Å
• c: 19.4285 ± 0.0007 Å
• α: 107.755 ± 0.0018°
• β: 93.746 ± 0.0018°
• γ: 91.4929 ± 0.0019°
• Cell volume: 5864.5 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0663
• Residual factor for significantly intense reflections: 0.0335
• Weighted residual factors for significantly intense reflections: 0.0657
• Weighted residual factors for all reflections included in the refinement: 0.0717
• Goodness-of-fit parameter for all reflections included in the refinement: 0.943
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No