Information card for entry 4342611

Structure parameters

• Formula: C34 H86 F6 N4 O8 S2 Si8 U2
• Calculated formula: C34 H86 F6 N4 O8 S2 Si8 U2
• SMILES: C[Si](C)(C)N([U]12([O]3CCCC3)(C[Si](C)(C)N1[Si](C)(C)C)[O]=S(O[U]1(C[Si](C)(C)N1[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)([O]=S(O2)(=O)C(F)(F)F)[O]1CCCC1)(=O)C(F)(F)F)[Si](C)(C)C
• Title of publication: U(III)-CN versus U(IV)-NC Coordination in Tris(silylamide) Complexes.
• Authors of publication: Hervé, Alexandre; Bouzidi, Yamina; Berthet, Jean-Claude; Belkhiri, Lotfi; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 5
• Pages of publication: 2474
• a: 11.8587 ± 0.001 Å
• b: 11.991 ± 0.001 Å
• c: 12.5171 ± 0.0009 Å
• α: 92.187 ± 0.005°
• β: 104.462 ± 0.005°
• γ: 114.001 ± 0.004°
• Cell volume: 1554.7 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0553
• Residual factor for significantly intense reflections: 0.0478
• Weighted residual factors for significantly intense reflections: 0.1246
• Weighted residual factors for all reflections included in the refinement: 0.1279
• Goodness-of-fit parameter for all reflections included in the refinement: 1.089
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No